张远飞
姓名:张远飞
学历、职称: 博士、副教授(硕士生导师)
Email: yfzhang@nnnu.edu.cn, yfzhang2015@sina.com
Tel: +86-18376766582
教育与研究经历:
2006-2010 重庆大学,药学专业,理学学士
2010-2015 中国科学院福建物质结构研究所,有机化学博士(硕博连读)
2015-2017 中国科学院福建物质结构研究所,助理研究员
2017-2018 以色列理工学院,博士后
2018-现在 南宁师范大学,化学与材料学院
研究兴趣
1、过渡金属催化有机合成新方法,着重研究反应的非对映与立体选择性及其在天然产物、药物与生物活性分子高效、简洁合成中的应用;
2、有机电化学合成反应。
催化化学与有机电化学合成实验室简介(B509):
B509配备有有机合成与电化学研究所需各种实验室设备,现有6名硕士研究生攻读硕士学位。实验室已经在Angew. Chem. Int. Ed、Org. Lett、Comm. Chem、Org. Chem. Front、J. Org. Chem等国际期刊发表数篇高水平论文,其中Angew. Chem. Int. Ed入选ESI top 1%高被引用论文、Org. Lett被Synfact重点评述。获得国家自然科学基金2项、广西自然科学基金2项资助。实验室每年计划招收1-2名硕士研究生,欢迎对有机化学、无机化学研究有兴趣的有志青年报考本实验室学术型研究生。
主持科研项目:
1. 国家自然科学基金青年基金;
2. 国家自然科学基金地区基金;
3. 广西自然科学基金青年基金;
4. 广西自然科学基金青年人才专项基金;
5. 南宁师范大学科研启动经费;
6. 结构化学国家重点实验室基金;
学术论文(* 通讯作者):
[1] Ying Song, Ruimin Li, Jintong Bai, Shuaikang Zhou, Yuanfei Zhang*, Carboxylic Acid-Enabled Vinylene Transfer Reaction by Co(III) Catalyst: Scope and Applications to the Five-Step Total Synthesis of Protoberberine Alkaloids Containing Free Hydroxyl Group without Protection. J. Org. Chem. 2024, 89, 3238-3250.
[2] Yanmin Huang, Qipeng Xiong, Xiangying Li, Yuanfei Zhang*, Chunfang Gan, Zining Peng, Linlin Wang, Jianguo Cui*, Synthesis, Characterization and Application of Emamectin-alkaline Lignin Conjugate with Photolysis Resistance and Systemic Translocation. Int. J. Biol. Macromol. 2023, 240, 124450.
[3] Yuanfei Zhang, Hao Wang, Jintong Bai, Qiuxia Liu, Jianguo Cui, and Yanmin Huang*, Rh(III)-Catalyzed Synthesis of Amino-isocoumarins with N‑Functionalized Cyclic Carbonates via C-H/O-H Annulation. Org. Lett. 2022, 24, 9222-9227.
[4] Yanmin Huang, Meizhen Wei, Zining Peng, Yang Cheng, Yuanfei Zhang*, Junyan Li, Junan Xiao, Chunfang Gan, Jianguo Cui*, Synthesis of estrone selenocyanate Compounds, anti-tumor activity evaluation and Structure-activity relationship analysis. Bioorg. Med. Chem. 2022. 76, 117086.
[5] Yuanfei Zhang*, Xinghua Li, Jintong Bai, Zhaoyu Huang, Minhai Yin, Jiarong Sheng*, Ying Song*, Rh(III)-catalyzed C-H Allylation/Annulative Markovnikov Addition with 5-Methylene-1,3-dioxan-2-one: Formation of Isoquinolinones Containing C3 Quaternary Centre, Org. Chem. Front. 2021, 72, 153049-153053.
[6] Yuanfei Zhang#, Zhe-Ning Chen#, Weiping Su*, Rhodium(III)-catalyzed Regioselective C-H Nitrosation/annulation of Unsymmetrical Azobenzenes to Synthesize Benzotriazole N-oxides via a RhIII/RhIII Redox-neutral Pathway, Tetrahedron Lett. 2021, 72, 153049-153053.
[7] Xinghua Li#, Ting Huang#, Ying Song, Yue Qi, Limin Li, Yanping Li, Qi Xiao*, Yuanfei Zhang*, Co(III)-Catalyzed Annulative Vinylene Transfer via C-H Activation: Three-Step Total Synthesis of 8-Oxopseudopalmatine and Oxopalmatine, Org. Lett. 2020, 22, 5925-5930. (Highlighted by Synfact 2020, 16(11): 1285, Highlighted by Organic Chemistry Portal)
[8] Yuanfei Zhang#, Zhe-Ning Chen#, Xiaofeng Zhang#, Xi Deng, Wei Zhuang*, Weiping Su*, Iodide-enhanced Palladium Catalysis via Formation of Iodide-bridged Binuclear Palladium Complex, Communications Chemistry, 2020, 3, 1-9.
[9] Yuanfei Zhang, Ting Huang, Xinghua Li, Min Zhang, Ying Song, Kelin Huang*, Weiping Su*, Rh(III)-Catalyzed Spiroannulation of 3-Arylquinoxalin-2(1H)-ones with Alkynes: Practical Access to Spiroquinoxalinones, RSC Adv. 2020, 10, 22216-22221.
[10] Yuanfei Zhang, Huaiqing Zhao, Min Zhang, Weiping Su*, Carboxylic Acids as Traceless Directing Groups for the Rhodium(III)-Catalyzed Decarboxylative C-H Arylation of Thiophenes. Angew. Chem. Int. Ed. 2015, 54, 3817-3821. (ESI 高被引论文)
[11] Yuanfei Zhang, Zhikai Chen, Wenliang Wu, Yuhong Zhang, Weiping Su*, CuI-Catalyzed Aerobic Oxidative α-Aminaton Cyclization of Ketones to Access Aryl or Alkenyl-Substituted Imidazoheterocycles. J. Org. Chem. 2013, 78, 12494-12504.
[12] Min Zhang, Yuanfei Zhang, Xiaoming Jie, Huaiqing Zhao, Gang Li*, Weiping Su*, Recent advances in directed C-H functionalizations using monodentate nitrogen-based directing groups. Org. Chem. Front. 2014, 1, 843-895.
[13] Changlei Zhu, Yuanfei Zhang, Jian Kan, Shijun Huang, Huaiqing Zhao*, Weiping Su*, Ambient-Temperature Ortho-C-H Arylation of Benzoic Acids with Aryl Iodides under Ligand-Supported Palladium Catalyst. Org. Lett. 2015, 17, 3418-3421.
[14] Cuiju Zhu, Yuanfei Zhang, Huaiqing Zhao, Shijun Huang, Min Zhang*, Weiping Su*, Sodium iodide-Catalyzed Direct α-Alkoxylation of Ketones with Alcohols via Oxidation of α-Iodo Ketone Intermediates. Adv. Synth. Catal. 2015, 357, 331-338.
[15] Minting Hao, Qianqian Hu,* Yuanfei Zhang, Mingbu Luo, Yanqi Wang, Bing Hu, Jianrong Li,* Xiaoying Huang, Inorg. Chem. 2019, 58, 5126-5133.
[16] Quanlong Zhou, Changlei Zhu, Ge Wu, Yuanfei Zhang, Min Zhang*, Weiping Su*, Construction of Carbazoles by Palladium-Catalyzed Direct Cross-Coupling of Indoles with in situ Generated Aryl Vinyl Ketones, Chin. J. Org. Chem. 2017, 37, 2655-2662.
[17] Hongyi Li, Quangdi Jiang, Xiaoming Jie, Yaping Shang, Yuanfei Zhang, Lucas J. Goossen*, Weiping Su*, Rh/Cu-Catalyzed Ketone β-Functionalization by Merging Ketone Dehydrogenation and Carboxyl-Directed C-H Alkylation, ACS Catal. 2018, 8, 4777-4782.